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Please clarify your complete question.
How do i unlock the Sim on the iphone 5?
Did you buy your phone used?
Yes i do have my iphone 5
How do I get a new SIM Card?
Call, chat or go to a Verizon store.
I was asking if you bought your iPhone used versus buying it new. At any rate, as mentioned you can just contact Verizon or visit a store to get a SIM card sent to you.